Home » Products » Functional solvent » Alcohol Ether Ester » Dmm/ Dipropylene Glycol Dimethyl Ether CAS: 111109-77-4 As a solvent in organic synthesis reactions

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Dmm/ Dipropylene Glycol Dimethyl Ether CAS: 111109-77-4 As a solvent in organic synthesis reactions

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Backed by a listed parent company (STAR Market 688133), TICHEM manufactures 99.5% pure DMM for industrial clients in organic synthesis and specialty coatings. This unique aprotic glycol diether contains no hydroxyl groups, making it ideal for proton-sensitive systems like water-based PU coatings and esterification reactions. Our 13+ years of functional solvent expertise and global partnerships ensure consistent high purity you can depend on.
Availability:

Model NO.: T101617

Composition

Organic

Type

Organic Compounds

Flux Type

Solvents

Usage

Medium

Grade

Industrial Grade/USP/Ep

Purity

99.5%

MOQ

1ton

Appearance

Colourless Transparent Liquid

Trademark

TICHEM

Transport Package

Iron Drum/IBC/ISO Tank

HS Code

2905320000

Origin

China

Dipropylene Glycol Dimethyl Ether (DMM), also known as DPGDME or Proglyde DMM, is a glycol diether with the molecular formula C8H18O3 and CAS number 111109-77-4. It is a colourless transparent liquid with a mild odour. Unlike glycol ethers that contain hydroxyl groups, DMM is an aprotic solvent, meaning it has no active hydroxyl (-OH) functionality in its molecular structure. This aprotic nature makes it chemically inert in many reaction systems that are sensitive to proton donors.

DMM offers good solvency for a wide range of organic compounds, along with moderate evaporation rate and good coupling performance. It is compatible with both polar and non-polar materials, and it shows stability across a broad pH range. These characteristics make DMM suitable for use in organic synthesis reactions, coating formulations, agricultural chemical preparations, and various industrial cleaning applications.

Technical Specifications of DMM CAS 111109-77-4

Property

Value

Molecular weight (g/mol)

162.23

Flash point (Setaflash Closed Cup)

149°F (65°C)

Boiling point @ 760 mmHg, 1.01 bar

347°F (175°C)

Freezing point

<71ºC

Specific gravity (25/25ºC)

0.092

Density @ 20ºC

0.903 g/cm³

Viscosity (cP or mPa•s @ 25ºC)

1.0

Specific heat (J/g/ºC @ 25ºC)

1.83

Autoignition temperature

165ºC

Surface tension (dynes/cm or mN/m @ 25ºC)

26.3

Evaporation rate (n-butyl acetate = 1.0)

0.13

Grade and Quality Notes

DMM is available in industrial grade with a minimum purity of 99.0% determined by gas chromatography. Higher purity grades, including USP and EP grades, may be available for specific regulated applications upon request and subject to minimum order requirements. Buyers should confirm grade suitability for their intended use prior to purchase.

Industrial Applications of DMM Glycol Diether

Aprotic Solvent for Water-Based Polyurethane Coatings

The aprotic nature of DMM makes it suitable for use in proton-sensitive coating systems, such as water-based polyurethane (PUD) coatings. Since DMM does not contain hydroxyl groups, it does not react with isocyanate components in two-component polyurethane systems, allowing it to function as a co-solvent that modifies viscosity and film formation without interfering with the curing chemistry. It can also improve the flow and leveling characteristics of waterborne coating formulations.

Solvent for Organic Synthesis and Esterification Reactions

In organic synthesis, DMM is used as a reaction solvent for various chemical processes. Its aprotic character and moderate boiling point make it suitable for reactions that require a non-protic medium with good solvency for both reactants and products. In esterification reactions, DMM can serve as an azeotroping solvent to remove water generated during the reaction, which helps drive the esterification equilibrium toward higher conversion and supports the production of clear resin products.

Component in Paint Strippers and Cleaning Formulations

DMM is used in paint stripping formulations, particularly those designed for removing cured coatings and epoxy residues. When combined with small amounts of protic co-solvents, it provides effective solvency for a range of coating films. It is also used in industrial cleaning products, including printed circuit board (PCB) cleaners, where its ability to dissolve flux residues while maintaining material compatibility with electronic components is valued. DMM's stability across a wide pH range allows its use in both acidic and alkaline cleaning formulations.

Solvent and Coupling Agent for Agricultural Formulations

DMM finds application in agricultural chemical formulations where its solvency, coupling performance, and compatibility with a range of active ingredients and adjuvants are utilized. It can serve as a co-solvent in emulsifiable concentrates (EC), microemulsions, and suspension concentrate formulations, helping to maintain formulation stability and uniform active ingredient distribution. Agricultural formulation developers typically conduct compatibility testing at intended usage rates before full-scale production.

Packaging, Storage and Handling

Packaging Options

DMM is available in multiple packaging formats to suit different order sizes:

Steel drums: 180 kg net weight per drum

IBC totes: 900 kg net weight per intermediate bulk container

ISO tank containers: For bulk volume shipments

All packaging complies with applicable chemical transport regulations. Custom labelling and dedicated packaging configurations can be arranged for enterprise customers with regular volume commitments.

Storage and Handling Guidelines

DMM should be stored in tightly sealed containers in a cool, well-ventilated warehouse area away from sources of heat, ignition, and direct sunlight. Although DMM has a moderate flash point, standard flammable liquid storage practices should be followed. Personnel handling the product should wear appropriate personal protective equipment, including chemical-resistant gloves and safety glasses. A complete Safety Data Sheet (SDS) is available and should be consulted before any handling, storage, or processing of this material.

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FAQ About DMM CAS 111109-77-4

What does "aprotic" mean and why does it matter?

An aprotic solvent is one that does not contain a readily transferable proton (hydrogen ion) and does not have hydroxyl (-OH) or amine (-NH) groups in its molecular structure. This matters in chemical systems where the presence of active protons would interfere with the desired reaction or curing process, such as in isocyanate-based polyurethane coatings or certain organic synthesis reactions. DMM's aprotic nature allows it to function as a solvent in these systems without participating in unwanted side reactions.

What is the minimum order quantity for DMM?

The standard MOQ is 1 metric ton for drum-packed orders. Orders in IBC totes or ISO tank containers are also available with corresponding minimum volume requirements. Evaluation samples in smaller quantities can be requested separately; please contact the sales team for current sample availability and pricing.

How does DMM differ from propylene glycol methyl ether (PM)?

DMM (Dipropylene Glycol Dimethyl Ether) is a diether with both end groups methylated, making it aprotic. PM (Propylene Glycol Methyl Ether) is a monoether with one hydroxyl group, making it protic. This fundamental difference in molecular structure leads to different solubility behaviours and different suitability for reaction-sensitive systems. DMM generally has a higher boiling point and lower water miscibility compared with PM.

What is the typical lead time for DMM orders?

Standard delivery lead time is 7 to 15 working days from order confirmation, depending on order size and current inventory status. Bulk ISO tank shipments may require additional logistics arrangement time. Customers with ongoing supply needs may discuss scheduled delivery programs or safety stock arrangements to support consistent production planning.

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  +86-400-690-7790 / +86-158-2157-4101
  jingyu.wang@titanchem.com
  Room 201-52, No. 64, Kangjian Road, Xuhui District, Shanghai
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